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A new composite anode, Fe–Cu–Si/C for lithium ion battery

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title A new composite anode, Fe–Cu–Si/C for lithium ion battery
 
Creator Doh, C.H.
Shin, H.M.
Kim, D.H.
Jeong, Y.D.
Moon, S.I.
Jin, B.S.
Kim, H.S.
Kim, K.W.
Oh, D.H.
Veluchamy, A.
 
Subject Lithium batteries
Electrochemical Power Sources
 
Description A new anode composite material comprising Fe, Cu and Si in conjunction with graphite has been obtained through high energy ball milling (HEBM) technique. The X-ray diffraction (XRD) analysis predicts that the milled composite particles remain in the elemental state and the scanning electron microscope (SEM) pictures show that the electrode annealed at 200 ◦C consists of well-defined aggregate particulates with interspaces. The composite electrode exhibits high initial discharge and charge capacity of 809 and 464 mAh g−1, respectively with a sustainable reversible capacity >385 mAh g−1 at 30th cycle and maintains high coulombic efficiency >95% after 4th cycle. As the annealing temperature is changed from 110 to >150 ◦C, the irreversible capacity increased from 158 to 340 mAh g−1.
 
Publisher Elsevier B.V.
 
Date 2008
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/219/1/071-2008.pdf
Doh, C.H. and Shin, H.M. and Kim, D.H. and Jeong, Y.D. and Moon, S.I. and Jin, B.S. and Kim, H.S. and Kim, K.W. and Oh, D.H. and Veluchamy, A. (2008) A new composite anode, Fe–Cu–Si/C for lithium ion battery. Journal of Alloys and Compounds, 461 (1-2). pp. 321-325. ISSN 0925-8388
 
Relation http://cecri.csircentral.net/219/