Conversion of Benzylic Bromides to Benzaldehydes Using Sodium Nitrate As an Oxidant
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
View Archive Info| Field | Value | |
| Title |
Conversion of Benzylic Bromides to Benzaldehydes Using Sodium Nitrate As an
Oxidant
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| Creator |
Kulangiappar, K.
Anbukulandainathan, M. Raju, T. |
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| Subject |
Electroorganic
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| Description |
A simple and effective approach for the synthesis of benzaldehydes from benzylic bromides is reported using
sodium nitrate as an oxidant with 10% sodium hydroxide. Benzyl bromide is oxidized to benzaldehyde in
91% yield with 98% conversion at 120 °C, whereas 82% of benzyl alcohol is obtained at a temperature of 80
°C in 80 min with 20% sodium nitrate solution.
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| Publisher |
American Chemical Society
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| Date |
2010
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/237/1/2010-041.pdf
Kulangiappar, K. and Anbukulandainathan, M. and Raju, T. (2010) Conversion of Benzylic Bromides to Benzaldehydes Using Sodium Nitrate As an Oxidant. Industrial Engineering & Chemical Research, 49. pp. 6670-6673. |
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| Relation |
http://cecri.csircentral.net/237/
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