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Mesoporous Carbon and Poly(3,4-ethylenedioxythiophene) Composite as Catalyst Support for Polymer Electrolyte Fuel Cells

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Mesoporous Carbon and Poly(3,4-ethylenedioxythiophene) Composite as Catalyst Support for Polymer Electrolyte Fuel Cells
 
Creator Tintula, K.K.
Sahu, A.K.
Shahid, A.
Pitchumani, S.
Sridhar, P.
Shukla, A.K.
 
Subject Fuel Cells
 
Description In situ polymerization of 3,4-ethylenedioxythiophene with sol–gel-derived mesoporous carbon (MC) leading to a new composite and its subsequent impregnation with Pt nanoparticles for application in polymer electrolyte fuel cells (PEFCs) is reported. The composite exhibits good dispersion and utilization of platinum nanoparticles akin to other commonly used microporous carbon materials, such as carbon black. Pt-supported MC–poly(3,4-ethylenedioxythiophene) (PEDOT) composite also exhibits promising electrocatalytic activity toward oxygen reduction reaction, which is central to PEFCs. The PEFC with Pt-loaded MC-PEDOT support exhibits 75% of enhancement in its power density in relation to the PEFC with Pt-loaded pristine MC support while operating under identical conditions. It is conjectured that Pt-supported MC–PEDOT composite ameliorates PEFC performance/ durability on repetitive potential cycling.
 
Publisher The Electrochemical Society
 
Date 2010
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/334/1/2010-080.pdf
Tintula, K.K. and Sahu, A.K. and Shahid, A. and Pitchumani, S. and Sridhar, P. and Shukla, A.K. (2010) Mesoporous Carbon and Poly(3,4-ethylenedioxythiophene) Composite as Catalyst Support for Polymer Electrolyte Fuel Cells. Journal of the Electrochemical Society, 157 (11). B1679-B1685. ISSN 0013-4651
 
Relation http://cecri.csircentral.net/334/