Electrochemical Behavior of LiM0.25Ni0.25Mn1.5O4 as 5 V Cathode Materials for Lithium Rechargeable Batteries
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
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| Title |
Electrochemical Behavior of LiM0.25Ni0.25Mn1.5O4 as 5 V
Cathode Materials for Lithium Rechargeable Batteries
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| Creator |
Rajakumar, S.
Thirunakaran, R. Sivashanmugam, A. Yamaki, J. Gopukumar, S. |
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| Subject |
Lithium batteries
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| Description |
Glycine-assisted sol-gel–synthesized multiple-doped spinels, LiM0.25Ni0.25Mn1.5O4 M = Cr, Fe, and Co have been studied as 5 V
cathode materials. The sol-gel technique provides homogeneity, high purity, lower processing temperature, controlled particle size,
and morphology. The synthesized samples were subjected to physical characterization studies, viz., thermogravimetric and differential
thermal analysis, X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and electrochemical
charge–discharge studies. Galvanostatic charge–discharge studies of the samples reveal that LiFe0.25Ni0.25Mn1.5O4 using glycine as
a chelating agent delivers a stable capacity of 120 mAh g−1 even after 20 cycles when cycled between 3 and 5 V.
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| Publisher |
The Electrochemical Society
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| Date |
2009
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/491/1/098-2009.pdf
Rajakumar, S. and Thirunakaran, R. and Sivashanmugam, A. and Yamaki, J. and Gopukumar, S. (2009) Electrochemical Behavior of LiM0.25Ni0.25Mn1.5O4 as 5 V Cathode Materials for Lithium Rechargeable Batteries. Journal of the Electrochemical Society, 156 (3). pp. 246-252. ISSN 0013-4651 |
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| Relation |
http://cecri.csircentral.net/491/
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