Phosphane-Free Green Protocol for Selective Nitro Reduction with an Iron-Based Catalyst
IR@IHBT: CSIR-Institute of Himalayan Bioresource Technology, Palampur
View Archive Info| Field | Value | |
| Title |
Phosphane-Free Green Protocol for Selective Nitro Reduction
with an Iron-Based Catalyst
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| Creator |
Sharma, U
Verma, P K Kumar, Neeraj Kumar, Vishal Bala , M Singh , Bikram |
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| Subject |
Plant sciences
Natural Product Chemistry |
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| Description |
Abstract: Iron phthalocyanine with
iron sulfate has been successfully applied
for high chemo- and regioselective
reduction of aromatic nitro compounds
to give the corresponding
amines in a green solvent system without
using any toxic ligand. The catalytic
systems were also compatible with a
large range of other reducible functional
groups, such as keto, acid, amide,
ester, halogen, lactone, nitrile, Nbenzyl,
O-benzyl, hydroxy, and heterocycles.
In the present study, dinitro
compounds have been regioselectively
reduced to the corresponding amines
with high yield. In most of the cases
the conversion and selectivity was
greater than 99% as determined by
GC-MS analysis.
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| Date |
2011
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://ihbt.csircentral.net/947/1/08%2D02%2D2012_Phosphane%2Dfree.pdf
Sharma, U and Verma, P K and Kumar, Neeraj and Kumar, Vishal and Bala , M and Singh , Bikram (2011) Phosphane-Free Green Protocol for Selective Nitro Reduction with an Iron-Based Catalyst. Chemistry-A European Journal , 17. pp. 5903-5907. |
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| Relation |
http://ihbt.csircentral.net/947/
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