Role of Arene Interactions and Substituents Effect in Conformational (syn/anti) Control of 1,2-Diarylethanes†‡
IR@CDRI: CSIR-Central Drug Research Institute, Lucknow
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Creator |
Avasthi, Kamlakar
Kumar, Amar Aswal, Sangeeta Kant, Ruchir Raghunandan, Resmi Maulik, P R Khanna, R S Ravikumar, Krishnan |
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Date |
2012-03-13T04:20:53Z
2012-03-13T04:20:53Z 2012 |
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Identifier |
CrystEngComm, 2012, 14, 383-388
http://hdl.handle.net/123456789/750 |
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Description |
Conformational analysis of nine designed flexible 1,2-diarylethanes with different substituents show syn conformation due to π–π interactions by 1H NMR in solution, this carries over to the solid state for three compounds while two show anti conformation in solid state by X-ray crystallography and remaining compounds do not give diffraction quality crystals.
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1493024 bytes
application/pdf |
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Language |
en
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Relation |
cdricommunicationo.8163
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Subject |
X-ray crystallography
diarylethanes |
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Title |
Role of Arene Interactions and Substituents Effect in Conformational (syn/anti) Control of 1,2-Diarylethanes†‡
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Type |
Article
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