A mild and efficient method for the oxidation of benzylic alcohols by two-phase electrolysis
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
View Archive Info| Field | Value | |
| Title |
A mild and efficient method for the oxidation of benzylic
alcohols by two-phase electrolysis
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| Creator |
Raju, T.
Manivasagan, S. Revathy, B. Kulangiappar, K. Muthukumaran, A. |
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| Subject |
Electroorganic
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| Description |
Electrochemical oxidation of benzylic and substituted benzylic alcohols by two-phase electrolysis yields the corresponding
aldehydes as products. The reaction was carried out in a single compartment cell with platinum electrodes at room temperature
in chloroform using an aqueous sodium bromide solution (25%) containing a catalytic amount of HBr. The two-phase electrolysis
resulted in high yields (74–96%) of benzaldehyde from primary alcohols and secondary alcohols were oxidized to the corresponding
ketone but only in low yields under these conditions.
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| Publisher |
Elsevier B.V
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| Date |
2007
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/852/1/136-2007.pdf
Raju, T. and Manivasagan, S. and Revathy, B. and Kulangiappar, K. and Muthukumaran, A. (2007) A mild and efficient method for the oxidation of benzylic alcohols by two-phase electrolysis. Tetrahedron Letters, 48. pp. 3681-3684. ISSN 0040-4039 |
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| Relation |
http://cecri.csircentral.net/852/
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