Synthesis and surface treatment of LiNi1/3Co1/3Mn1/3O2 cathode materials for Li-ion batteries
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
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Title |
Synthesis and surface treatment of LiNi1/3Co1/3Mn1/3O2
cathode materials for Li-ion batteries
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Creator |
Fey, G.T.K.
Chang, C.S. Premkumar, T. |
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Subject |
Lithium batteries
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Description |
In order to shorten process time and possibly reduce
synthesis cost of LiNi1/3Co1/3Mn1/3O2, the cathode material
was prepared by solution combustion and microwave
synthesis routes with reduced duration of calcination. The
products were also surface-modified with Al2O3 by a
mechano-thermal coating process to enhance cyclability.
The structure and morphology of the bare and the surfacemodified
LiNi1/3Co1/3Mn1/3O2 samples were characterized
by X-ray diffraction, field-emission scanning electron microscopy,
transmission electron microscopy, energy-dispersive
spectroscopy, and differential scanning calorimetry
techniques. At a 0.1-C rate and between 4.6 and 2.5 V, the
products delivered a first-cycle discharge capacity of as much
as 195 mA h/g. Surface modification of LiNi1/3Co1/3Mn1/3O2
with alumina resulted in improved cyclability.
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Publisher |
Springer-Verlag
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Date |
2010
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Type |
Article
PeerReviewed |
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Format |
application/pdf
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Identifier |
http://cecri.csircentral.net/485/1/2010-102.pdf
Fey, G.T.K. and Chang, C.S. and Premkumar, T. (2010) Synthesis and surface treatment of LiNi1/3Co1/3Mn1/3O2 cathode materials for Li-ion batteries. Journal of Solid State Electrochemistry, 14. pp. 17-26. ISSN 1432-8488 |
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Relation |
http://cecri.csircentral.net/485/
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