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Vanadyl ion stability in silica gels

IR@CGCRI: CSIR-Central Glass and Ceramic Research Institute, Kolkata

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Field Value
 
Title Vanadyl ion stability in silica gels
 
Creator Sujatha Devi, P
Ganguli, Dibyendu
 
Subject Engineering Materials
 
Description Silica gels doped with vanadium were prepared from tetra ethyl orthosilicate and an aqueous solution of NH4VO3, at a final sol pH of 1.5-2.5. Absorption and electron paramagnetic resonance (EPR) spectral studies establish that under ambient conditions the incorporated pentavalent vanadium is stabilized as tetravalent vanadyl ion in the gel monoliths. Dried gels were very stable under ambient conditions, however, transformation of V4+ to V5+ was noted during gel densification. (C) 1998 Elsevier Science B.V. All rights reserved.
 
Publisher Elsevier
 
Date 1998-10
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cgcri.csircentral.net/1564/1/sujatha.pdf
Sujatha Devi, P and Ganguli, Dibyendu (1998) Vanadyl ion stability in silica gels. Journal of Non-Crystalline Solids, 240 (1-3). pp. 50-54. ISSN 0022-3093
 
Relation http://cgcri.csircentral.net/1564/