Synthesis, structure determination and reactivity of a highly stable vanadium(III) complex
IR@CGCRI: CSIR-Central Glass and Ceramic Research Institute, Kolkata
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| Title |
Synthesis, structure determination and reactivity of a highly stable vanadium(III) complex
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| Creator |
Chatterjee, Modhumita
Ghosh, Saktiprosad Nandi, Asok Kumar |
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| Subject |
Microstructure and Characterization
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| Description |
The synthesis, characterization, structure determination and reactivity study of a highly stable vanadium(III) complex of picolinic acid (picH)-a monoacid bidentate chelating donor-is reported. It can be kept in open air for days and can be heated up to 180 degrees C without oxidation. The complex [V(pic)(3)]. H2O crystallizes in the monoclinic system with space group C2/c. The V-III acceptor centre is in a highly distorted octahedral donor environment. The reason for this exceptional stability of the complex towards oxidation is evident from the analysis of the structural and electrochemical data. (C) 1997 Elsevier Science Ltd.
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| Publisher |
Pergamon-Elsevier
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| Date |
1997
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cgcri.csircentral.net/1606/3/madhumita.pdf
Chatterjee, Modhumita and Ghosh, Saktiprosad and Nandi, Asok Kumar (1997) Synthesis, structure determination and reactivity of a highly stable vanadium(III) complex. Polyhedron, 16 (17). pp. 2917-2923. ISSN 0277-5387 |
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| Relation |
http://cgcri.csircentral.net/1606/
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