Eco-friendly kinetic separation of trans-limonene and carvomenthene oxides.
IR@CFTRI: CSIR-Central Food Technological Research Institute, Mysore
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http://ir.cftri.com/11645/
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| Title |
Eco-friendly kinetic separation of trans-limonene and carvomenthene oxides.
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| Creator |
Santosh Kumar, S. C.
Manjunatha, J. R. Srinivas, P. Bettadaiah, B. K. |
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| Subject |
24 Organic Chemistry
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| Description |
Kinetic separation of trans-limonene oxide and trans-carvomenthene oxide was achieved in high
yield by selective ring opening of their cis-epoxides in the presence of InCl3 catalyst in water. Catalytic activity
of InCl3 was conserved up to 10 cycles. Nucleophilic addition of methanol in presence of InCl3 was also selective
as cis-epoxides preferentially reacted leaving behind trans-epoxides, which were separated by fractional
distillation.
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| Date |
2014
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Language |
en
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| Rights |
—
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| Identifier |
http://ir.cftri.com/11645/1/J.%20Chem.%20Sci.%20126%283%29_2014_875.pdf
Santosh Kumar, S. C. and Manjunatha, J. R. and Srinivas, P. and Bettadaiah, B. K. (2014) Eco-friendly kinetic separation of trans-limonene and carvomenthene oxides. Journal of Chemical Sciences, 126 (3). pp. 875-880. |
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