CSIR Central

Structure and mutarotation of ascorbic acid osazones.

IR@CFTRI: CSIR-Central Food Technological Research Institute, Mysore

View Archive Info
 
 
Field Value
 
Relation http://ir.cftri.com/5534/
 
Title Structure and mutarotation of ascorbic acid osazones.
 
Creator Rao, J. M.
Nair, P. M.
 
Subject 24 Organic Chemistry
 
Description study of ascorbic acid osazones by spectroscopic methods shows that they are y-lactones, not Mactones as claimed recently. It is found that they mutarotate in solution. Mutarotation involves geometric isomerization of the hydrazone moieties and replacement of one chelate system by another. The path for isomerization is discussed.
 
Date 1970
 
Type Article
PeerReviewed
 
Format pdf
 
Language en
 
Identifier http://ir.cftri.com/5534/1/Tetrahedron%20Vol%2026.%20pp.%203833%20to%203838.pdf
Rao, J. M. and Nair, P. M. (1970) Structure and mutarotation of ascorbic acid osazones. Tetrahedron, 26. pp. 3833-3838.