Isomerization of beta-HCH in aqueous solution.
IR@CFTRI: CSIR-Central Food Technological Research Institute, Mysore
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http://ir.cftri.com/8622/
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Title |
Isomerization of beta-HCH in aqueous solution.
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Creator |
Deo, P. G.
Hasan, S. B. Majumder, S. K. |
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Subject |
26 Pesticide Chemistry
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Description |
PESTAB. beta-HCH (beta-BHC) was purified by recrystallization and 5 mg were reacted with 125 ml autoclaved distilled H2O for various time intervals at 25 +- 1C. The filtrate was examined by GLC and was found to contain alpha, beta, gamma (lindane) and delta-BHC isomers as well as some unidentified compounds. An instantaneous dehydrochlorination of beta-BHC in distilled water was also observed. The acetone extract of the filtrate was further shaken for 4 days and bioassay toxicity studies were performed on mosquito and flour-beetle larvae and on houseflies. The toxicity of the extract was significantly greater than equal amounts of untreated beta-BHC in acetone. The results indicate beta-BHC may isomerize in aquatic environments and therefore, may be a potential source of more biologically active isomers in the environment.
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Date |
1980
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Type |
Article
PeerReviewed |
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Format |
pdf
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Language |
en
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Identifier |
http://ir.cftri.com/8622/1/J.%20ENVIRON.%20SCI.%20HEALTH%2C%20B15%282%29%2C%20147-164%20%281980%29.pdf
Deo, P. G. and Hasan, S. B. and Majumder, S. K. (1980) Isomerization of beta-HCH in aqueous solution. Journal of Environmental Science Health B, 15 (2). 147-164; 15 ref.. |
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