RuO4 catalyzed dihydroxylation for the synthesis of mixed medium-chain triacylglycerols.
IR@CFTRI: CSIR-Central Food Technological Research Institute, Mysore
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| Relation |
http://ir.cftri.com/13809/
https://doi.org/10.1016/j.tetlet.2015.04.008 |
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| Title |
RuO4 catalyzed dihydroxylation for the synthesis of mixed
medium-chain triacylglycerols.
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| Creator |
Nandini, K.
Srinivas, P. Bettadaiah, B. K. |
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| Subject |
17 Fatty Acid Chemistry
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| Description |
RuO4 catalyzed dihydroxylation of allyl acylates (C5 to C12) to glyceryl acylates is reported. The dihydroxylation was a major product (61–85%) with C5–C7 whereas carbonyl compounds by double bond fission were major with C8–C12 systems. 1-Hexanoylglycerol, obtained in high yields (85%), was further acylated with medium chain fatty acid chlorides to prepare mixed medium chain triglycerides (85–90%). Hence, a facile preparation of triacylglycerols such as C6–C6–C6, C6–C8–C8, C6–C10–C10, and C6–C12–C12 is accomplished.
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| Date |
2015
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| Type |
Article
PeerReviewed |
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| Format |
pdf
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| Language |
en
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| Identifier |
http://ir.cftri.com/13809/1/Tetrahedron%20Letters%20Volume%2056%20issue%2021%202015%20%5Bdoi%2010.1016%252Fj.tetlet.2015.04.008%5D%20Nandini%2C%20K.%3B%20Srinivas%2C%20P.%3B%20Bettadaiah%2C%20B.K.%20--%20RuO4%20catalyzed%20dihydroxylation%20for%20the%20synthesis%20of%20mixed%20medium-chain%20t.pdf
Nandini, K. and Srinivas, P. and Bettadaiah, B. K. (2015) RuO4 catalyzed dihydroxylation for the synthesis of mixed medium-chain triacylglycerols. Tetrahedron Letters, 56 (21). pp. 2704-2706. |
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